Photoinitiators

Photoinitators

A photoinitiator is a compound that undergoes a photoreaction on absorption of light, producing reactive species. These are capable of initiating or catalyzing chemical reactions that result in significant changes in the solubility and physical properties of suitable formulations.

For over 30 years, Hampford Research Inc. has manufactured free radical photoinitiators based on the hexaaryl-bisimidazolyl (HABI) molecule. Through careful modification of the substituents on the aryl groups, HRI has been able to significantly improve the performance at 365, 395 & 405 nm, the wavelength most commonly emitted by LED lights. These innovative new compounds will still produce stable lophyl radicals and offer resistance to oxygen inhibition that HABI’s are known for.

All HABI photoinitiators operate via a Norrish II type reaction mechanism, meaning they must be combined with a suitable co-initiator in order attain complete photo-polymerization. Hampford Research experts can help you choose the ideal combination for your application.

The high molecular weight as well as the low polarity of the HABI molecule makes it ideal for applications where low migration characteristics are paramount.

HABI, for LED applications is sold exclusively under the LEDCUR tradename.

For more information, or to request samples please CLICK HERE.

HRI Prod. #NameDescriptionCAS Number
FP5067BDK

Free radical photoinitiator designed for most UV curable applications

24650-42-8
FP5380o-Cl HABI/BCIM

Free radical photoinitiator with outstanding heat stability

7189-82-4
FP5385LEDCUR 110

Free radical photoinitiator optimized for use with 360 nm LED lamps

29864-18-4
FP53882-Carboxy HABI

Water soluble free radical photoinitiator

2243458-25-3
FP5450TCDM HABIFree radical photoinitiator optimized for use with 385 nm LED lamps100486-97-3

Photoacid Generators

Photoacids are molecules which become more acidic upon absorption of light. This is due either to the formation of strong acids upon photodissociation, or to the dissociation of protons upon photoassociation (e.g. ring-closing). There are two main types of molecules that release protons upon illumination: photoacid generators (PAGs) and photoacids (PAHs). PAGs undergo proton photodissociation irreversibly, while PAHs are molecules that undergo proton photodissociation and thermal reassociation. In this case the excited state is strongly acidic, but reversible.

For more information, or to request samples please Click Here.
HRI Prod. #Product nameProduct DescriptionCAS Number
FP5028Bis (4-Cumyl) Iodonium Tetraphenyl BoratePhotoacid generator1158840-74-4
FP5035Bis (4-t-butylphenyl) Iodonium HexafluorophosphatePhotoacid generator61358-25-6
FP5041Bis (4-t-butylphenyl) Iodonium TetraphenylboratePhotoacid generator131725-16-1
FP5386OPPIPhotoacid generator121239-75-6
FP5374LEDCUR 210LPhotoacid generator71786-70-4